2.1.3 · D5Quantum Atomic Structure

Question bank — Dual nature of matter — de Broglie λ = h - p

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The one rule everything here tests: — Planck's constant on top, momentum below. Wave nature is loud only when is comparable to the size of whatever the particle meets.


True or false — justify

Every moving particle, even a resting-then-pushed dust speck, has a de Broglie wavelength.
True — the instant it has non-zero momentum it has . Only a truly stationary object () has no finite wavelength ().
A photon has zero rest mass, so it cannot have a de Broglie wavelength.
False — the relation needs momentum, not rest mass. A photon carries , so , its ordinary wavelength.
Doubling a particle's speed doubles its de Broglie wavelength.
False — speed sits in the denominator, so doubling halves . Faster ⇒ shorter wave.
Two particles with the same kinetic energy always have the same de Broglie wavelength.
False — also depends on mass, so a heavier particle at equal has a shorter wavelength.
A proton and an electron accelerated through the same voltage get the same wavelength.
False — both gain the same (same ), but ; the heavier proton has the much shorter wavelength.
The matter wave physically wiggles the particle up and down like a vibrating string.
False — it is a probability/guiding wave; its amplitude squared tells you where the particle is likely to be, not a mechanical vibration of the particle itself.
A cricket ball has no de Broglie wavelength at all.
False — it has one (~ m), it is just so absurdly small that no slit or crystal can diffract it, so we never observe waviness.
If a particle slows to a stop its de Broglie wavelength shrinks to zero.
False — as , , so (grows without bound). Slow means long, not short, wavelength.

Spot the error

"For an electron I'll use since appeared in the derivation."
Wrong: belonged to the photon (which alone travels at light speed). For matter use the particle's own speed : .
"The electron gains eV, so I plug straight into ."
Error: eV must be converted to joules first (). Mixing eV with SI mass and gives nonsense units.
"Heavier objects carry more matter, so they must have longer matter waves."
Error: mass is in the denominator of . More mass ⇒ shorter wavelength — which is precisely why big objects show no wave behaviour.
"Since was derived using , matter waves must travel at the speed of light."
Error: only the derivation's analogy borrowed a photon. A matter wave is associated with a slow particle; nothing forces it to move at .
"An electron microscope beats a light microscope because electrons are smaller than photons."
Error: size isn't the reason. It's wavelength — an accelerated electron's nm is far shorter than visible light's nm, and shorter means finer resolution.
" can be used to find the kinetic energy of a slow electron."
Error: holds only for massless particles (photons). For matter use or the full .

Why questions

Why does de Broglie's argument start from light rather than from matter?
Because for light both (Planck) and (relativity) were already experimentally established; combining them gives , which de Broglie then extended to matter by symmetry.
Why does the formula suggest it need not be limited to photons?
It contains only , , and — no term that says "must be light." Anything with momentum fits, which is the whole leap of the hypothesis.
Why do we almost never notice the wave nature of everyday objects?
Their momentum is enormous compared to , giving wavelengths near m — far too small to diffract off any real obstacle.
Why did physicists test the hypothesis with electrons fired at crystals?
An accelerated electron's (~Å) matches atomic spacing in a crystal, the only "slit" fine enough to reveal diffraction — see Davisson–Germer Experiment.
Why does wave nature make an exact position and momentum impossible at once?
A wave with a definite wavelength (definite ) is spread out in space (uncertain position); pinning position localises the wave and blurs — this is Heisenberg Uncertainty Principle.
Why does the de Broglie idea support Bohr's quantised orbits?
A stable orbit must fit a whole number of electron wavelengths, ; otherwise the wave interferes with itself destructively — linking to Bohr Model of Atom.
Why does the matter-wave picture naturally lead to Schrödinger's ?
Once a particle is a wave, you need an equation governing that wave's shape and evolution — that equation is the Schrödinger Wave Equation, whose replaces the guiding wave.

Edge cases

What is the de Broglie wavelength of a genuinely stationary particle ()?
It is undefined/infinite: makes blow up, meaning no localised wave — the concept only applies to moving particles.
What happens to as a particle's speed approaches the speed of light?
Momentum grows relativistically without bound, so — the wave becomes vanishingly short and the particle looks purely particle-like.
For a neutral particle like a neutron, does the accelerating-voltage formula apply?
No — needs a charge to gain energy from a field. A neutron has , so you must know its or speed directly.
Compare the wavelength of a slow electron and a fast electron of equal mass.
The slow one has the longer wavelength, since ; slower momentum means a bigger, more spread-out wave.
At the same speed, which is wavier — an electron or a proton?
The electron, because it is ~1800× lighter; smaller gives larger , so its wave behaviour is far easier to observe.
Is there any object too heavy to have a matter wave?
No object is exempt — every moving mass has one; heavy objects simply have wavelengths so tiny they can never be measured, so "no wave" really means "immeasurably small wave."

Recall Quick self-test before you move on

Cover these and answer aloud. If I halve the mass but keep speed fixed, does what? ::: Doubles — mass is in the denominator. Why can't a football diffract through a doorway? ::: Its m is unimaginably smaller than the doorway, so no bending occurs. Photon momentum with zero rest mass — contradiction? ::: No: momentum comes from energy via , not from rest mass.


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