1.7.6Thermodynamics

Heat transfer — conduction (Fourier's law k), convection, radiation (Stefan-Boltzmann σT⁴)

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1. Conduction — Fourier's Law

WHAT we want: the rate of heat flow dQdt\dfrac{dQ}{dt} (the heat current HH, units W) through a slab.

HOW we build the formula (derivation from scratch):

Think of a slab of cross-section AA, thickness Δx\Delta x, with hot face at T1T_1 and cold face at T2T_2 (T1>T2T_1>T_2).

  1. Heat current must grow with area AA — twice the wall, twice the flow. So HAH\propto A.
  2. It must grow with the temperature difference ΔT=T1T2\Delta T = T_1-T_2 — steeper drop pushes more heat. So HΔTH\propto \Delta T.
  3. It must shrink with thickness Δx\Delta x — a thicker wall slows it. So H1/ΔxH\propto 1/\Delta x.

Combine and insert a material constant kk to fix the units:

H=dQdt=kAΔTΔxH = \frac{dQ}{dt} = kA\,\frac{\Delta T}{\Delta x}

In the limit of a continuous gradient this is the proper Fourier's law:


2. Convection

  • Natural convection: driven by buoyancy (density differences) alone.
  • Forced convection: fluid pushed by a fan/pump.

Newton's law of cooling (engineering model): H=hA(TsTfluid)H = hA(T_s - T_{\text{fluid}}) where hh is the convection coefficient (W m⁻² K⁻¹), TsT_s the surface temperature.


3. Radiation — Stefan–Boltzmann Law

WHY the 4th power: integrating Planck's blackbody spectrum over all frequencies gives a total emitted power T4\propto T^4. The key consequence: doubling absolute temperature multiplies radiated power by 24=162^4 = 16.

Figure — Heat transfer — conduction (Fourier's law k), convection, radiation (Stefan-Boltzmann σT⁴)

Common Mistakes (Steel-man + Fix)


Active Recall

#flashcards/physics

State Fourier's law of conduction with the meaning of every symbol.
H=kAdT/dxH=-kA\,dT/dx; HH=heat current (W), kk=thermal conductivity, AA=area, dT/dxdT/dx=temperature gradient; minus = flow toward cold.
What are the three modes of heat transfer and what carries energy in each?
Conduction (atomic collisions/electrons, no bulk motion), convection (moving fluid carries it), radiation (EM waves, no medium needed).
Why does conduction not occur with bulk motion of matter but convection does?
Conduction = energy passed between fixed/touching molecules; convection = hot fluid physically flows to a new place.
Define thermal resistance and how it combines in series vs parallel.
R=Δx/(kA)R=\Delta x/(kA); series → resistances add; parallel → conductances (1/R1/R) add.
State the Stefan–Boltzmann law and the value of σ.
P=eσAT4P=e\sigma A T^4, σ=5.67×108\sigma=5.67\times10^{-8} W m⁻² K⁻⁴, TT in kelvin.
Why is total radiated power proportional to T4T^4?
Integrating Planck's blackbody spectrum over all wavelengths gives total power ∝ T4T^4.
Write the NET radiation exchange formula and justify it.
Pnet=eσA(T4T04)P_{net}=e\sigma A(T^4-T_0^4); body emits eσAT4e\sigma AT^4, absorbs eσAT04e\sigma AT_0^4 from surroundings (Kirchhoff: same ee).
If absolute temperature triples, radiated power changes by what factor?
34=813^4=81 times.
Why must radiation use kelvin but Fourier's law can use °C?
T4T^4 is absolute (power of T); Fourier uses only a difference ΔT\Delta T, which is identical in °C and K.
State Newton's law of cooling for convection.
H=hA(TsTfluid)H=hA(T_s-T_{fluid}), hh=convection coefficient.

Recall Feynman: explain to a 12-year-old

Imagine a hot bowl of soup. Conduction is like a line of kids holding hands passing a hot potato hand to hand — nobody moves, the heat hops along. Convection is one kid grabbing the hot potato and running to the cold side — the carrier itself moves. Radiation is the potato so hot it glows, and you feel its warmth on your face from across the room — that warmth flew through empty air as invisible light. The glowing one follows a sneaky rule: make it twice as hot (in true kelvin), and it shines sixteen times brighter.

Connections

Concept Map

drives

via

via

via

no bulk motion

moving fluid carries energy

EM waves no medium

contains

rewritten as

analogy

series adds

Heat transfer hot to cold

2nd law of thermo

Conduction

Convection

Radiation

Fourier's law H = -kA dT/dx

Thermal conductivity k

Thermal resistance R = dx/kA

Ohm's law for heat

Stefan-Boltzmann sigma T^4

Hinglish (regional understanding)

Intuition Hinglish mein samjho

Dekho, heat transfer ke sirf teen tareeke hain. Conduction mein heat solid ke andar atom-se-atom collision se travel karti hai — matter khud move nahi karta, bas energy aage badhti hai (jaise garam chamach). Iska rule Fourier's law hai: H=kAΔT/ΔxH=kA\,\Delta T/\Delta x. Matlab zyada area, zyada temperature difference, aur patli wall → zyada heat flow. Yahan kk material ka apna property hai (metal ka high, gas/air ka bahut low — isiliye air gap achha insulator hai).

Convection mein fluid (liquid ya gas) khud bahta hai aur heat ko le jaata hai — garam fluid halka hoke upar uthta hai, thanda neeche aata hai, ek loop ban jaata hai. Yeh solid mein nahi ho sakta kyunki solid bah nahi sakta. Engineering formula: H=hA(TsTfluid)H=hA(T_s-T_{fluid}).

Radiation sabse mast hai — yeh EM waves se jaati hai, koi medium chahiye hi nahi! Isi liye Sun ki garmi vacuum cross karke Earth tak aati hai. Iska law Stefan–Boltzmann: P=eσAT4P=e\sigma A T^4. Sabse important baat: yahan TT hamesha kelvin mein lo, kyunki yeh TT ka fourth power hai — agar temperature double karoge to power 24=162^4=16 guna ho jaati hai! Yeh chhoti si galti (°C use karna) exam mein sabse zyada marks katwaati hai.

Yaad rakho: jab bhi TT ka power lena ho (radiation), kelvin; jab sirf difference ΔT\Delta T chahiye (conduction), °C aur K dono same kaam karte hain. Bas yahi 80/20 trick hai poora chapter samajhne ke liye.

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Connections