2.2.9Doping & PN Junctions

Diode I-V characteristic curve

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WHAT is the I-V curve?

The whole curve is captured by the Shockley diode equation:

I=IS(eV/(nVT)1)I = I_S\left(e^{V/(nV_T)} - 1\right)

  • ISI_S = reverse saturation current (tiny, ~101210^{-12} A for Si)
  • nn = ideality factor (1–2, ≈1 ideal)
  • VT=kT/qV_T = kT/q = thermal voltage (≈ 25.85 mV at 300 K)
Figure — Diode I-V characteristic curve

WHY does it look like this? (Derivation from scratch)

The PN junction has a built-in depletion region with a potential barrier. Carriers must climb this barrier to cross. The number of carriers with enough thermal energy to climb an energy barrier ΔE\Delta E follows Boltzmann statistics:

n(can cross)eΔE/kTn(\text{can cross}) \propto e^{-\Delta E / kT}

Step 1 — barrier at equilibrium. With no bias, diffusion current (carriers climbing) exactly cancels drift current (carriers rolling back). Call the balanced drift current ISI_S.

Why this step? At equilibrium net current must be zero, so the two flows are equal and opposite — this pins the reference current to ISI_S.

Step 2 — apply forward voltage VV. Forward bias lowers the barrier by energy qVqV. New diffusion current:

Idiff=ISeqV/kTI_{\text{diff}} = I_S\, e^{qV/kT}

Why this step? Lowering barrier energy by qVqV multiplies the Boltzmann factor by eqV/kTe^{qV/kT}, so exponentially more carriers cross.

Step 3 — drift current unchanged. Drift depends on minority carriers swept by the field, whose supply is limited, not on the barrier height. So it stays at ISI_S (flowing the other way):

I=IdiffIdrift=ISeqV/kTIS=IS(eqV/kT1)I = I_{\text{diff}} - I_{\text{drift}} = I_S e^{qV/kT} - I_S = I_S\left(e^{qV/kT}-1\right)

Step 4 — define VT=kT/qV_T=kT/q and insert ideality nn for real (non-ideal) recombination:

I=IS(eV/(nVT)1)\boxed{I = I_S\left(e^{V/(nV_T)}-1\right)}


The knee (turn-on) voltage

There is no single true threshold — the exponential is smooth — but practically the current becomes "noticeable" around:

  • Silicon: Vγ0.7V_\gamma \approx 0.7 V
  • Germanium: 0.3\approx 0.3 V
  • LED (varies): 1.8–3.3 V

Worked Examples


Common Mistakes


Flashcards

Shockley diode equation
I=IS(eV/(nVT)1)I = I_S\left(e^{V/(nV_T)} - 1\right)
What is VTV_T and its value at 300 K?
Thermal voltage kT/q25.85kT/q \approx 25.85 mV
Why is the forward I-V exponential?
Barrier-crossing carriers follow Boltzmann eqV/kTe^{qV/kT}; voltage lowers the barrier exponentially
Reverse-bias current value
IS\approx -I_S (reverse saturation / leakage), tiny and roughly constant
What does nn (ideality factor) represent?
Non-ideality from recombination; 1 (ideal) to 2
Voltage change per decade of current (60 mV rule)
VTln1059.6V_T\ln 10 \approx 59.6 mV
Invert Shockley for V
V=nVTln(I/IS+1)V = nV_T\ln(I/I_S + 1)
Why can we drop the "−1" in forward bias?
Because eV/nVT1e^{V/nV_T}\gg 1 once VnVTV\gg nV_T
Silicon vs Germanium knee voltage
Si ≈ 0.7 V, Ge ≈ 0.3 V
What happens beyond reverse breakdown VBRV_{BR}?
Large reverse current flows (avalanche/Zener); diode conducts backwards
Effect of temperature on ISI_S
Increases (roughly doubles per ~10 °C), raising leakage

Recall Feynman: explain to a 12-year-old

Imagine a gate at the top of a hill and a crowd of kids trying to cross. Normally the hill is too tall — only a few super-energetic kids make it (that's the tiny leakage). If you push the gate to make the hill shorter (forward voltage), suddenly WAY more kids can climb over — and every little bit shorter you make it, ten times as many rush through. Push the wrong way and you make the hill taller, so almost nobody crosses. That "almost nobody, then suddenly a flood" is exactly the diode curve.


Connections

  • PN Junction — the barrier whose lowering is the exponential
  • Depletion Region — where the potential barrier lives
  • Boltzmann Distribution — source of the eqV/kTe^{qV/kT} term
  • Thermal VoltageVT=kT/qV_T=kT/q
  • Zener Diode — engineered breakdown region
  • Doping — sets ISI_S and barrier height
  • Diode Circuit Models — the 0.7 V approximation of this curve

Concept Map

carriers climb via

gives exponential

plots as

region V>0

region V<0

region V<-Vbr

current rises after

shows

tiny leakage

contains

contains

each 60mV

PN junction barrier

Boltzmann statistics

Shockley diode equation

I-V characteristic curve

Forward bias

Reverse bias

Breakdown

Knee voltage

Exponential rise

Reverse saturation Is

Thermal voltage Vt = kT/q

Ideality factor n

current x10

Hinglish (regional understanding)

Intuition Hinglish mein samjho

Dekho, diode ka I-V curve basically ek one-way valve ka fingerprint hai. Agar tum forward bias doge (anode positive), toh current pehle kaafi der tak lagbhag zero rehta hai, aur phir ~0.7 V ke aas-paas achanak exponentially phatt se badhne lagta hai. Isko "knee" ya turn-on voltage bolte hain. Reverse bias me current lagbhag zero (bas thoda sa leakage IS-I_S) rehta hai, jab tak breakdown na aa jaye.

Yeh exponential kyun? Kyunki PN junction me ek energy barrier hota hai, aur sirf wahi carriers cross kar paate hain jinke paas kaafi thermal energy ho — yeh Boltzmann eΔE/kTe^{-\Delta E/kT} follow karta hai. Jab tum forward voltage lagate ho, barrier neeche aata hai, aur har chhoti si voltage badhne pe carriers ki sankhya exponentially badhti hai. Poora rishta ek hi equation me: I=IS(eV/nVT1)I = I_S(e^{V/nV_T}-1), jahan VT=kT/q26V_T=kT/q \approx 26 mV room temperature pe.

Ek fatafat trick yaad rakho: current ko 10 guna karne ke liye sirf ~60 mV extra voltage chahiye (VTln10V_T \ln 10). Isiliye curve itna steep dikhta hai. Aur ek common galti se bacho — 0.7 V koi "brick wall" nahi hai; uske neeche bhi current behta hai, bas microamps me, isliye nazar nahi aata. Reverse me bhi "bilkul zero" nahi, thoda leakage hamesha rehta hai jo temperature ke saath badhta hai.

Exam aur circuits dono ke liye yeh curve base hai — rectifier, clipper, LED, Zener sab isi exponential nature se samajh aate hain. Formula ko derive karke yaad rakho, ratna mat.

Test yourself — Doping & PN Junctions

Connections