2.2.5Doping & PN Junctions

Depletion region and space charge

2,069 words9 min readdifficulty · medium2 backlinks

WHAT is happening?

WHY does it form?

  1. Free electrons are dense on the n-side, holes dense on the p-side.
  2. Concentration gradient → diffusion. Electrons diffuse into the p-side, holes into the n-side.
  3. They recombine, wiping out mobile carriers near the boundary.
  4. The now-uncovered fixed dopant ions can't move — they stay put as space charge.
  5. This charge makes an E-field pointing n→p which pushes carriers back (drift).
  6. Equilibrium = drift exactly cancels diffusion. Net current = 0.
Figure — Depletion region and space charge

HOW to derive the field, potential, and width

We use Poisson's equation in 1D. This is the master tool — everything else falls out.

WHY this equation? Gauss's law says charge creates diverging field (E=ρ/ε\nabla\cdot E = \rho/\varepsilon). In 1D that's dE/dx=ρ/εsdE/dx = \rho/\varepsilon_s. And E=dϕ/dxE = -d\phi/dx by definition of potential.

Step 1 — The depletion approximation

Assume the space charge is a clean box: fully depleted inside, neutral outside. ρ(x)={qNAxp<x<0 (p-side)+qND0<x<xn (n-side)\rho(x) = \begin{cases} -qN_A & -x_p < x < 0 \ (\text{p-side}) \\ +qN_D & 0 < x < x_n \ (\text{n-side}) \end{cases}

Why this step? Real carrier profiles are smooth, but treating the edges as sharp turns messy integrals into simple ones — and it's accurate because carriers vanish fast (over a Debye length).

Step 2 — Charge neutrality

The whole crystal is neutral, so total positive = total negative charge: qNAxp=qNDxn==NAxp=NDxn==qN_A x_p = qN_D x_n \quad\Rightarrow\quad ==N_A x_p = N_D x_n==

Why this step? No net charge was created — we only rearranged it. So the exposed positive and negative charge must balance. Consequence: the depletion region extends further into the lightly-doped side.

Step 3 — Integrate for the E-field

Integrate dE/dx=ρ/εsdE/dx = \rho/\varepsilon_s. On the p-side (ρ=qNA\rho=-qN_A), with E=0E=0 at x=xpx=-x_p: E(x)=qNAεs(x+xp),xp<x<0E(x) = -\frac{qN_A}{\varepsilon_s}(x + x_p), \qquad -x_p < x < 0 On the n-side (ρ=+qND\rho=+qN_D), with E=0E=0 at x=xnx=x_n: E(x)=qNDεs(xnx),0<x<xnE(x) = -\frac{qN_D}{\varepsilon_s}(x_n - x), \qquad 0 < x < x_n

The field is maximum at the junction (x=0x=0), triangular in shape: Emax=qNAxpεs=qNDxnεsE_{max} = -\frac{qN_A x_p}{\varepsilon_s} = -\frac{qN_D x_n}{\varepsilon_s}

Why this step? The field starts at zero at the edges (neutral region), grows linearly through each charged slab, and peaks at the metallurgical junction. The two expressions match at x=0x=0 because of Step 2's neutrality.

Step 4 — Integrate for the potential (built-in voltage)

VbiV_{bi} is the area under the E|E| vs xx curve (a triangle): Vbi=xpxnEdx=12EmaxWV_{bi} = -\int_{-x_p}^{x_n} E\,dx = \frac{1}{2}|E_{max}|\,W where W=xp+xnW = x_p + x_n is the total width.

Step 5 — Solve for the total width

Substitute xp,xnx_p, x_n (from neutrality) into Vbi=12EmaxWV_{bi}=\tfrac12|E_{max}|W and solve: W=2εsVbiq(1NA+1ND)\boxed{W = \sqrt{\frac{2\varepsilon_s V_{bi}}{q}\left(\frac{1}{N_A}+\frac{1}{N_D}\right)}}

Why this form? Higher VbiV_{bi} → wider region (more charge needed to build the field). Higher doping → narrower region (fewer ions needed to expose the same charge).


Worked Examples


Common Mistakes


Active Recall

Recall Feynman: explain to a 12-year-old

Imagine a room split in half. The left half is packed with red balls (holes) and the right half with blue balls (electrons). Open the door in the middle: the balls rush to the emptier side and pair up, vanishing. But each ball that leaves uncovers a fixed magnet stuck to the floor (the dopant ion) — red balls leave behind negative magnets, blue balls leave behind positive ones. These stuck magnets create an invisible "wind" that eventually blows so hard it stops any more balls from crossing. That calm empty strip in the middle, full of stuck magnets but no free balls, is the depletion region.

Flashcards

What is the depletion region?
A junction zone depleted of mobile carriers, containing only fixed ionized dopant ions (space charge).
What charge remains on the n-side of the depletion region?
Positive donor ions (ND+N_D^+).
What charge remains on the p-side?
Negative acceptor ions (NAN_A^-).
What is the charge-neutrality condition?
NAxp=NDxnN_A x_p = N_D x_n.
Which side does the depletion region extend further into?
The lightly-doped side.
What starting equation derives E-field and potential in the junction?
Poisson's equation d2ϕ/dx2=ρ/εsd^2\phi/dx^2 = -\rho/\varepsilon_s.
What is the shape of the E-field vs position?
Triangular — linear in x, maximum at the metallurgical junction.
Formula for built-in potential?
Vbi=(kT/q)ln(NAND/ni2)V_{bi} = (kT/q)\ln(N_A N_D / n_i^2).
Formula for total depletion width?
W=(2εsVbi/q)(1/NA+1/ND)W = \sqrt{(2\varepsilon_s V_{bi}/q)(1/N_A + 1/N_D)}.
How does reverse bias affect width?
Widens it; replace VbiV_{bi} with Vbi+VRV_{bi}+V_R, so WVbi+VRW\propto\sqrt{V_{bi}+V_R}.
How does forward bias affect width?
Narrows it; use VbiVFV_{bi}-V_F.
Net current through the junction at equilibrium?
Zero — diffusion current exactly cancels drift current.
Why does the depletion width shrink with heavier doping?
Fewer ions are needed to expose the same charge, so the region is thinner (W1/NW\propto 1/\sqrt N effect).

Connections

  • Doping (Donors and Acceptors) — supplies the NAN_A, NDN_D ions that become the space charge.
  • Built-in Potential and Fermi Level Alignment — the thermodynamic origin of VbiV_{bi}.
  • Poisson's Equation and Gauss's Law — the mathematical engine of this derivation.
  • Diode I-V Characteristics — depletion behavior under forward/reverse bias.
  • Junction Capacitance and VaractorsCj=εsA/WC_j = \varepsilon_s A / W, directly from the width.
  • Drift and Diffusion Currents — the two balancing currents at equilibrium.

Concept Map

concentration gradient

electrons meet holes

removes mobile carriers

leaves behind

forms

creates E-field n to p

integrates to

pushes carriers back

cancels diffusion

solves

simplifies rho x

constrains width

p-n junction contact

Diffusion of carriers

Recombination near boundary

Depletion region

Fixed ionized dopant cores

Space charge

Built-in E-field

Built-in potential Vbi

Drift current

Equilibrium, net current 0

Poisson equation

Depletion approximation

Charge neutrality NA xp = ND xn

Hinglish (regional understanding)

Intuition Hinglish mein samjho

Dekho, jab p-type aur n-type semiconductor ko jodte ho, toh junction ke paas electrons (n-side se) aur holes (p-side se) ek dusre ki taraf diffuse karte hain kyunki concentration gradient hota hai. Yeh mil ke recombine ho jaate hain, aur peechhe reh jaate hain fixed ionized dopant atoms — n-side pe positive donor ions, p-side pe negative acceptor ions. Yeh carriers-se-khaali strip hi hai depletion region, aur inn fixed ions ka charge hi space charge kehlata hai.

Ab yeh exposed charge ek electric field banata hai jo n se p ki taraf point karta hai. Yeh field carriers ko wapas dhakelta hai (drift). Jab drift aur diffusion barabar ho jaate hain, tab equilibrium aa jaata hai aur net current zero ho jaata hai. Field ka shape triangular hota hai — junction pe maximum, edges pe zero — kyunki charge distributed hai, isliye Poisson's equation se EE linearly badhta hai.

Important baat: neutrality condition NAxp=NDxnN_A x_p = N_D x_n. Iska matlab depletion region us side mein zyada ghusti hai jahan doping kam hai. Yaad rakho: "light doping = long reach". Aur width ka formula W=(2εsVbi/q)(1/NA+1/ND)W=\sqrt{(2\varepsilon_s V_{bi}/q)(1/N_A+1/N_D)} — heavy doping se width chhoti, high voltage se badi. Reverse bias lagao toh Vbi+VRV_{bi}+V_R ho jaata hai aur region choda ho jaata hai; forward bias lagao toh VbiVFV_{bi}-V_F hoke region patli ho jaati hai aur current flow karne lagta hai. Yahi diode ka core funda hai.

Go deeper — visual, from zero

Test yourself — Doping & PN Junctions

Connections