This page belongs under the parent topic and pushes the numbers all the way through. Nothing here contradicts the parent — we just walk every case the topic can throw at you, one worked example per cell.
Before we begin, one promise: every symbol below was defined in the parent, but we re-anchor each one in plain words the first time it appears here, so you never meet a letter you haven't been introduced to.
Think of this whole topic as a machine with a few knobs. The knobs are: which material (governed by carrier density n — re-anchored just below), temperature T , geometry (L , A ), and doping . Each cell below is one twist of a knob into a corner case. The examples that follow hit every cell.
Three symbols show up in the matrix (rows G, H and beyond), so let's re-anchor them before you meet them in the table:
Definition Carrier density
n , conductivity σ , mobility μ (plain words)
==Carrier density n == (units m − 3 , "how many per cubic metre") is the head-count of free charges — the electrons (and holes) actually able to move and carry current inside one cubic metre of the material. This single number is what separates the three classes: conductors have a huge n , insulators almost none, semiconductors a small but tunable n .
==Conductivity σ == (units S/m , "siemens per metre") is a material's willingness to carry current — literally the inverse of resistivity, σ = 1/ ρ . Big σ = easy flow.
==Mobility μ == (units m 2 / ( V ⋅ s ) ) is how fast a carrier drifts per unit of electric push — nimble carriers have high μ .
Together they build the master formula σ = n e μ , where e is the charge on one carrier.
Cell
What is being tested
Corner it probes
Example
A
Classify by resistivity ρ
tiny ρ (conductor edge)
Ex 1
B
Classify by resistivity ρ
huge ρ (insulator edge)
Ex 2
C
Geometry: R = ρ L / A
ordinary shaped wire
Ex 3
D
Geometry limits
degenerate: both R → 0 and R → ∞
Ex 4
E
Temperature — semiconductor
T up → ρ down
Ex 5
F
Temperature — metal
T up → ρ up (opposite sign)
Ex 6
G
Doping ratio
n jumps by orders of magnitude
Ex 7
H
Microscopic σ = n e μ (conductivity from n , e , μ )
build σ from scratch
Ex 8
I
Real-world word problem
pick a material for a job
Ex 9
J
Exam twist / zero input
n → 0 limiting behaviour
Ex 10
Two more quantities do the geometry work, so let's re-anchor them once:
Definition The two "R" words (don't mix them)
==Resistivity ρ == (units Ω ⋅ m ) is a material-only number — how stubbornly the stuff itself fights current, regardless of shape.
==Resistance R == (units Ω , ohms) is what a specific object shows, so it depends on shape: R = ρ L / A , where L is the length the current travels and A is the cross-section it flows through.
Picture ρ as "how muddy the field is" and R as "how tiring this particular path across the field is."
Prerequisite links if you need them: Ohm's Law and Resistance , Electric Charge and Current , Energy Bands in Solids , Temperature Coefficient of Resistance , Semiconductor Diodes and Transistors .
Worked example Example 1 — Is
ρ = 2 × 1 0 − 8 Ω ⋅ m a conductor?
Forecast: Guess first — conductor, semiconductor, or insulator? Which one owns the "1 0 − 8 " neighbourhood?
Step 1 — Read the number's scale. The exponent is − 8 .
Why this step? Across the three classes, resistivity spans 24 orders of magnitude . The exponent alone almost always classifies — the leading digit barely matters.
Step 2 — Match to the parent's table. Conductors sit near 1 0 − 8 Ω ⋅ m ; copper is 1.7 × 1 0 − 8 .
Why this step? ρ is the sharpest single discriminator, sharper than "does it feel metallic."
Answer: 2 × 1 0 − 8 Ω ⋅ m → conductor (essentially copper-like).
Verify: Ratio to copper = 2 × 1 0 − 8 /1.7 × 1 0 − 8 ≈ 1.18 — same order of magnitude, so the label is safe.
Worked example Example 2 — Is
ρ = 5 × 1 0 12 Ω ⋅ m a conductor, semiconductor, or insulator?
Forecast: The exponent is + 12 . Which corner of the table lives up there?
Step 1 — Read the scale. 1 0 12 sits inside the insulator band (1 0 10 –1 0 16 ).
Why this step? Same logic as Ex 1 — let the exponent decide.
Step 2 — Sanity via carrier count. Insulators have n ≈ 0 free carriers (electrons present but stuck behind a > 5 eV gap).
Why this step? A second, independent reason (physics, not just the table) guards against a mislabel.
Answer: Insulator — this is glass-like territory.
Verify: It is 5 × 1 0 12 /1 0 − 8 = 5 × 1 0 20 times more resistive than a conductor — a factor no semiconductor (1 0 − 4 –1 0 3 ) could reach. Confirmed insulator.
Worked example Example 3 — Aluminium wire resistance
Aluminium, ρ = 2.8 × 1 0 − 8 Ω ⋅ m , length L = 10 m , cross-section area A = 2 × 1 0 − 6 m 2 . Find R .
Forecast: Bigger or smaller than 1 ohm? Guess before computing.
Step 1 — Choose the geometry formula. Use R = ρ A L .
Why this step? We asked about this object , not the raw material, so shape (L and A ) must enter. Look at the figure: the current runs along the red length L and squeezes through the mint face A .
Step 2 — Substitute.
R = 2 × 1 0 − 6 2.8 × 1 0 − 8 × 10 = 2 × 1 0 − 6 2.8 × 1 0 − 7 = 0.14 Ω.
Why this step? Longer wire (bigger L ) pushes R up; fatter wire (bigger A ) pulls R down — the formula encodes both, exactly as the figure's arrows suggest.
Answer: R = 0.14 Ω .
Verify (units): m 2 ( Ω ⋅ m ) ( m ) = Ω . ✓ A tenth of an ohm is tiny — correct for a metal.
Worked example Example 4 — Push the geometry to both extremes
Use copper, ρ = 1.7 × 1 0 − 8 Ω ⋅ m , throughout. Ask four things: what does R = ρ L / A do as (i) L → 0 , (ii) A → ∞ , (iii) L → ∞ , (iv) A → 0 ?
Forecast: Two of these send R to zero and two send R to infinity — sort them before reading on.
Step 1 — The two R → 0 limits. In R = ρ L / A , length L is in the numerator and area A in the denominator. So L → 0 gives R → 0 , and A → ∞ gives R → 0 .
Why this step? No length means no distance for collisions to accumulate; a huge area is like millions of wires in parallel. Both make resistance vanish — this is why chip interconnects are short and power buses are fat.
Step 2 — The two R → ∞ limits. Flip each: L → ∞ puts an unbounded numerator over a fixed denominator, so R → ∞ ; A → 0 puts a fixed numerator over a vanishing denominator, so R → ∞ .
Why this step? An infinitely long wire is endless collisions; a needle-thin wire squeezes all the current through almost nothing. Both choke the flow completely.
Step 3 — A concrete point between the extremes. For ρ = 1.7 × 1 0 − 8 , L = 0.001 m , A = 1 × 1 0 − 6 m 2 :
R = 1 × 1 0 − 6 1.7 × 1 0 − 8 × 0.001 = 1.7 × 1 0 − 5 Ω.
Why this step? A short, ordinary-area copper wire lands very close to the R → 0 corner — a real number to anchor the limits.
Step 4 — Cross-check against a longer wire (self-contained). Take the same copper but with L = 2 m , A = 1 × 1 0 − 6 m 2 :
R = 1 × 1 0 − 6 1.7 × 1 0 − 8 × 2 = 3.4 × 1 0 − 2 Ω = 0.034 Ω.
Why this step? Comparing two wires that differ only in length isolates the L dependence cleanly.
Answer: L → 0 and A → ∞ give R → 0 ; L → ∞ and A → 0 give R → ∞ . The concrete short wire is 1.7 × 1 0 − 5 Ω ; the 2 m wire is 0.034 Ω .
Verify: 0.034 Ω/1.7 × 1 0 − 5 Ω = 2000 , exactly the length ratio 2 m /0.001 m = 2000 . ✓ Longer = proportionally more resistive, confirming the L → ∞ direction.
The figure plots relative carrier density n (vertical axis, normalised so n = 1 at 300 K) against temperature T in kelvin (horizontal axis). The lavender curve is n ∝ e − E g / ( 2 k B T ) : notice how flat it is at low T (almost no electrons have climbed the gap) and how it swings sharply upward as T rises — that steep bend is the whole story of thermal excitation across the band gap. The mint dot marks the reference point at 300 K (n = 1 ); the coral dot marks 350 K, sitting about 21× higher . The shaded region beneath the curve is the growing population of freed electron–hole pairs. Read it as: warm the crystal a little, and the head-count of mobile carriers balloons — so resistivity falls.
Worked example Example 5 — Heat silicon from 300 K to 350 K
Silicon's band gap E g = 1.1 eV . Carrier density follows n ∝ e − E g / ( 2 k B T ) , where k B is Boltzmann's constant. In electron-volt units k B = 8.617 × 1 0 − 5 eV/K . By what factor does n grow going from T 1 = 300 K to T 2 = 350 K ?
Forecast: A modest 50 K warm-up — factor of ~2? ~10? ~100? Guess.
Step 1 — Why the exponential e − E g / ( 2 k B T ) ? Electrons must be thermally kicked across the gap. The exponential is the tool that answers "what fraction of particles has enough thermal energy to clear an energy wall?" — nothing linear captures that steepness. The factor of 2 in the exponent is because each freed electron leaves a hole , so the gap energy is shared between the electron–hole pair . See the figure: the tiny climbing population balloons with T .
Step 2 — Form the ratio to kill the unknown constant.
n 1 n 2 = exp [ − 2 k B E g ( T 2 1 − T 1 1 ) ] .
Why this step? The proportionality constant is unknown, but it cancels in a ratio — a standard trick.
Step 3 — Plug numbers.
2 k B E g = 2 ( 8.617 × 1 0 − 5 ) 1.1 = 6383 K .
T 2 1 − T 1 1 = 350 1 − 300 1 = − 4.762 × 1 0 − 4 K − 1 .
n 1 n 2 = exp [ − 6383 × ( − 4.762 × 1 0 − 4 ) ] = exp ( 3.039 ) ≈ 20.9.
Answer: Carriers jump about 21-fold for a mere 50 K rise.
Verify: Since σ = n e μ scales with n , conductivity rises ~21× → resistivity falls ~21×. Correct sign for a semiconductor.
Worked example Example 6 — Copper heated from 20 °C to 100 °C
Copper's temperature coefficient of resistance is α = 0.0039 K − 1 , using the linear law ρ ( T ) = ρ 0 [ 1 + α ( T − T 0 ) ] . Start at T 0 = 20 ∘ C with ρ 0 = 1.7 × 1 0 − 8 Ω ⋅ m . Find ρ at 100 ∘ C .
Forecast: Does copper's ρ go up or down? (Careful — this is the trap case.)
Step 1 — Choose the linear metal law, not the exponential. For a metal, n is fixed (bands already overlap); heat only makes ions vibrate more, so electrons collide more, shortening the average collision time τ . Since μ = e τ / m , mobility drops and ρ rises linearly over ordinary ranges.
Why this step? Wrong law = wrong sign. Metal ↑T → ρ ↑; semiconductor ↑T → ρ ↓. See Temperature Coefficient of Resistance .
Step 2 — Substitute Δ T = 80 K .
ρ = 1.7 × 1 0 − 8 [ 1 + 0.0039 × 80 ] = 1.7 × 1 0 − 8 × 1.312 = 2.23 × 1 0 − 8 Ω ⋅ m .
Answer: ρ ≈ 2.23 × 1 0 − 8 Ω ⋅ m — higher than the cold value.
Verify: Increase factor = 1 + 0.0039 × 80 = 1.312 , i.e. a 31.2% rise. Opposite direction to the silicon in Ex 5 — exactly the contrast the parent warns about.
Worked example Example 7 — Doping silicon
Intrinsic (pure) silicon has n i = 1.5 × 1 0 16 m − 3 free carriers. Dope it with phosphorus to n d = 5 × 1 0 22 m − 3 . By what factor does conductivity rise? (Assume e and mobility μ roughly unchanged.)
Forecast: Thousands? Millions? Guess the order of magnitude.
Step 1 — Use σ = n e μ . With e and μ fixed, σ is directly proportional to n .
Why this step? Doping's whole job is to change only n — the knob that separates the three classes.
Step 2 — Take the ratio.
σ i σ d = n i n d = 1.5 × 1 0 16 5 × 1 0 22 ≈ 3.33 × 1 0 6 .
Answer: Conductivity jumps about 3.3 million-fold from a pinch of impurity.
Verify: log 10 ( 3.33 × 1 0 6 ) ≈ 6.52 — a leap of over six decades, dwarfing anything temperature alone (Ex 5's ~21×) could do. That controllability is why silicon computes, not copper. See Semiconductor Diodes and Transistors .
Worked example Example 8 — Compute
σ and ρ of doped silicon from n , e , μ
Take n = 5 × 1 0 22 m − 3 , elementary charge e = 1.6 × 1 0 − 19 C , electron mobility μ = 0.14 m 2 / ( V ⋅ s ) . Find σ , then ρ .
Forecast: Will ρ land in the semiconductor band (1 0 − 4 –1 0 3 )?
Step 1 — Assemble σ = n e μ .
Why this step? This is the master formula — each factor is a physical count: n carriers, each of charge e , each moving with mobility μ (drift speed per unit field).
σ = ( 5 × 1 0 22 ) ( 1.6 × 1 0 − 19 ) ( 0.14 ) = 1120 S/m .
Step 2 — Invert for resistivity. ρ = 1/ σ .
Why this step? Resistivity is just the reciprocal — "stubbornness" is the inverse of "willingness."
ρ = 1120 1 ≈ 8.93 × 1 0 − 4 Ω ⋅ m .
Answer: σ ≈ 1120 S/m , ρ ≈ 8.9 × 1 0 − 4 Ω ⋅ m .
Verify: 8.9 × 1 0 − 4 sits at the low edge of the semiconductor band (1 0 − 4 –1 0 3 ) — sensible for heavily doped silicon. Units: m − 3 ⋅ C ⋅ m 2 V − 1 s − 1 = V ⋅ s ⋅ m C = V ⋅ m A = m S . ✓
Worked example Example 9 — Pick the material for a phone charger cable core vs. its outer sheath
A charger cable must (a) carry current through its core with almost no heat loss, and (b) be safe to touch on the outside. Choose ρ -appropriate materials for each part, and justify with power loss P = I 2 R . Use copper for the core, ρ Cu = 1.7 × 1 0 − 8 Ω ⋅ m , with length L = 10 m and cross-section A = 2 × 1 0 − 6 m 2 , carrying I = 2 A .
Forecast: Which class goes inside, which goes outside?
Step 1 — Core: minimise R to minimise heat. Power wasted as heat is P = I 2 R , and R = ρ L / A . To keep P low we need tiny ρ → a conductor ; we pick copper (ρ Cu = 1.7 × 1 0 − 8 ).
Why this step? Heat loss scales linearly with R , hence with ρ ; conductors minimise it.
Step 2 — Sheath: maximise R so no current reaches your hand. We want ρ enormous → an insulator (rubber/PVC, ρ ∼ 1 0 13 ).
Why this step? A large gap (> 5 eV) keeps electrons stuck, blocking leakage current.
Step 3 — Quantify the copper core loss. First the core resistance, using the copper ρ from the statement:
R = ρ Cu A L = 2 × 1 0 − 6 1.7 × 1 0 − 8 × 10 = 0.085 Ω.
Then the wasted power:
P = I 2 R = ( 2 ) 2 ( 0.085 ) = 0.34 W .
Why this step? We now use a single, consistent material (copper) end-to-end — no material swap mid-problem.
Answer: Copper core (low ρ ), rubber sheath (high ρ ); core resistance 0.085 Ω , core loss ≈ 0.34 W .
Verify: If we foolishly used a semiconductor core with ρ = 8.9 × 1 0 − 4 (Ex 8) at the same geometry , its R would be 8.9 × 1 0 − 4 /1.7 × 1 0 − 8 ≈ 5.2 × 1 0 4 times larger — dumping tens of kilowatts as heat. That is exactly why we choose a conductor.
Worked example Example 10 — What is
ρ of a perfect insulator as n → 0 ?
An idealised insulator has essentially no free carriers, n → 0 . Using ρ = 1/ ( n e μ ) , what happens to ρ ? And what does σ do?
Forecast: Does ρ go to 0 or to ∞ ?
Step 1 — Track σ = n e μ as n → 0 . With n → 0 , the product n e μ → 0 , so σ → 0 .
Why this step? Conductivity is a count of moving charges; no carriers means no conduction.
Step 2 — Invert. ρ = 1/ σ → 1/0 → + ∞ .
Why this step? Reciprocal of zero blows up — a perfect insulator has infinite resistivity in this idealisation.
Sanity on the physics: real insulators aren't literally infinite; a few carriers always sneak across the gap, so ρ is huge but finite (1 0 10 –1 0 16 ).
Step 3 — Contrast the conductor limit. As n → ∞ , σ → ∞ and ρ → 0 — the perfect conductor.
Answer: n → 0 ⇒ σ → 0 , ρ → ∞ (ideal insulator); n → ∞ ⇒ ρ → 0 (ideal conductor).
Verify: Test with a small-but-nonzero n = 1 0 6 m − 3 , e = 1.6 × 1 0 − 19 , μ = 0.1 : σ = 1.6 × 1 0 − 14 S/m , so ρ = 6.25 × 1 0 13 Ω ⋅ m — squarely in the insulator band. The limit direction is confirmed.
Recall Quick self-test on the matrix
Metal heated: ρ up or down? ::: Up (fixed n , more collisions, τ falls)
Pure semiconductor heated: ρ up or down? ::: Down (n ∝ e − E g /2 k B T grows fast)
Which knob does doping turn? ::: The carrier density n (raises σ = n e μ )
As n → 0 , resistivity ρ tends to? ::: Infinity (ideal insulator)
As A → 0 or L → ∞ , resistance R tends to? ::: Infinity
Does R = ρ L / A care about material only? ::: No — it also depends on shape (L , A )
Mnemonic One-line summary of every cell
"Same ρ , different R ; same material, different T can flip the sign — but only n ever changes the class."