1.7.1 · D5Thermodynamics

Question bank — Temperature — thermal equilibrium, thermometers, scales

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Why does gas pressure track temperature at all? (read before the traps)


True or false — justify

A hotter object always contains more thermal energy than a cooler one.
False — energy also depends on how much stuff there is; a huge lake at 20 °C holds vastly more thermal energy than a hot needle at 500 °C. Temperature is intensive, energy is extensive.
If two objects are at the same temperature, no heat can flow between them even if they touch.
True — equal temperature means they are in thermal equilibrium, so the net heat flow is zero (see Zeroth Law of Thermodynamics).
Doubling the Celsius temperature of a gas doubles its absolute temperature.
False — the scales have different zeros. Going from 20 °C to 40 °C takes the gas from 293 K to 313 K, nowhere near double, so "doubling" is only meaningful on the Kelvin scale.
A temperature change of 30 °C equals a change of 30 K.
True — Celsius and Kelvin degrees are the same size (100 divisions between ice and steam on both); the +273.15 offset cancels for any difference.
The metal railing feels colder than the wooden bench beside it, so it is at a lower temperature.
False — outdoors both sit at air temperature; metal just conducts heat out of your hand faster, so touch reports conductivity, not temperature.
Absolute zero is the temperature at which an ideal gas's pressure would extrapolate to zero at constant volume.
True — the straight line of versus hits at °C, and since an ideal gas cannot have negative pressure, that extrapolated crossing marks the hard floor K.
A thermometer measures the temperature of your body directly.
False — it measures its own temperature after reaching equilibrium with you; the Zeroth Law is what lets us then claim that reading is your temperature too.
Every liquid thermometer gives exactly the same reading between its fixed points.
False — different liquids expand slightly non-linearly and disagree between the fixed points; only dilute (ideal) gases agree, which is why the gas thermometer defines the absolute scale.

Spot the error

"To convert a 15 °C rise in reaction temperature to Fahrenheit, compute °F."
The is an origin shift, valid only for absolute readings, not differences. A change converts as °F.
"The triple-point definition works for any thermometric property like the length of a mercury column."
It only gives an absolute scale when the property genuinely goes to zero at ; a mercury column has finite length at absolute zero, so this proportional form is properly reserved for gas pressure or volume, which do vanish there.
"Since is in equilibrium with and is in equilibrium with , heat will now flow from to ."
The Zeroth Law says the opposite — and are already in equilibrium with each other, so no net heat flows between them.
"We only need one fixed point because two straight lines always cross once."
A linear law has two unknowns; one point cannot fix both slope and intercept. The single-fixed-point SI definition works only because it also fixes the intercept at zero by decree ( as ).
"Body temperature 37 °C converts to °F."
The origin shift was dropped; you must add 32, giving °F. Skipping the +32 confuses an interval with an actual reading.
"At absolute zero all molecular motion and all energy vanish completely."
Classically motion stops, but quantum mechanics leaves a residual zero-point energy; absolute zero is the state of minimum energy, not literally zero energy (link to Kinetic Theory of Gases).

Why questions

Why do we prefer a gas thermometer over a mercury one as the standard?
Because all dilute gases behave universally at low pressure and agree between the fixed points, whereas different liquids expand non-linearly and disagree, so the gas thermometer removes the choice-of-substance ambiguity.
Why is the Zeroth Law needed before we can even define temperature?
It guarantees that thermal equilibrium is transitive, so all mutually-equilibrated systems share one consistent number; without transitivity, "the temperature of an object" would not be a well-defined property.
Why do we assume the thermometer relation is linear rather than some curve?
Picture drawing a ruler on the thermometer: one mark alone tells you nothing about spacing, but two marks let you cut the gap into equal steps and extend those steps outward — that is exactly what "linear" means, a fixed step size all the way along. It is the simplest, most reproducible ruler you can build, and any smoothly-rising property can be defined to be linear in ; the price is that different substances then disagree slightly between the marks.
Why can't an ideal gas be cooled below °C?
Look at the extrapolated line in the -versus- figure: it reaches zero pressure at °C, and an ideal gas cannot push with negative pressure, so there is no lower state to reach — this is a true floor, not an arbitrary scale origin that could dip negative.
Why does a swimming pool at 30 °C melt more ice than a cup of tea at 90 °C?
Heat transferred depends on internal energy content, not temperature; the pool's enormous mass carries far more thermal energy despite its lower temperature (see Heat and Internal Energy).
Why do Celsius and Fahrenheit read the same value only at ?
The two scales are straight lines with different slopes, so they can only meet once. Setting the readings equal, , we move the across: , i.e. , so . Geometrically that is the single point where the C-line and F-line cross (see the C-vs-F figure below).

Edge cases

What temperature does a constant-volume gas thermometer read when its gas pressure is exactly zero?
K — the proportional definition forces at , which is absolute zero and physically unreachable for a real gas.
Two objects are placed in thermal contact and, after a while, none of their macroscopic properties (temperature, pressure, volume) change any further. What can you conclude?
They have reached thermal equilibrium, so their temperatures are now equal and no net heat flows between them — but this describes the settled state, not the whole history; heat may well have flowed earlier before things stopped changing.
Can two objects be in thermal equilibrium yet exchange matter or do work on each other?
No — thermal equilibrium is defined for thermal contact only (heat can pass, but no work or matter exchange); allowing those would introduce other imbalances.
For an interval, does converting Celsius to Kelvin ever require adding 273.15?
No — for a change exactly, because the offset cancels in any difference; the +273.15 applies only to converting an absolute reading.
Is there a temperature at which Kelvin and Celsius read the same number?
No finite one — they differ by a constant 273.15 everywhere, so their straight lines are parallel and never cross (unlike C and F, whose different slopes let them meet at ).
Doesn't "pressure can never be negative" contradict real materials that show negative pressure?
For an ideal gas it holds — a gas can only push. But condensed phases (a stretched liquid in a capillary, sap in tall trees) can sit in metastable negative-pressure states where they are under tension; that is a real, subtle effect and does not affect the ideal-gas extrapolation used to define absolute zero.
Recall One-line self-test

Temperature is intensive and sets the direction of heat flow; heat is extensive energy in transit. Confuse those two and half of these traps snap shut on you.