5.2.5 · D5Nuclear & Radiochemistry
Question bank — Nuclear reactions — Q-value, cross-section
True or false — justify
Verdict and one line of reasoning. No bare yes/no.
A positive Q always means the reaction happens spontaneously the instant particles are near.
False. only says energy would be released; a charged projectile may still need to climb (or tunnel through) the Coulomb barrier to get close enough, so probability (the question) is separate from the energy (the question).
For an exoergic reaction () there is no threshold energy.
True (in principle for neutral projectiles). With the products can already move as required, so is meaningless — no minimum kinetic energy is demanded; a charged projectile still faces a Coulomb barrier, which is a separate effect.
The Q-value depends on whether you compute it in the lab frame or the centre-of-mass frame.
False. is a difference of rest masses times — a frame-independent quantity. Only how the kinetic energy is shared changes between frames, not itself.
A reaction with (products heavier) releases energy.
False. Heavier products mean mass was gained, so : energy must be supplied. Only mass lost becomes released kinetic energy.
Cross-section can be larger than the geometric cross-sectional area of the nucleus.
True. is a quantum probability measure; at a resonance it can exceed the physical area by thousands of times (and far below threshold it can nearly vanish), because it counts how likely the reaction is, not how big the nucleus is.
Doubling the flux doubles the cross-section .
False. is a property of the nucleus–projectile pair at a given energy; it does not know about beam intensity. Doubling doubles the rate , leaving unchanged.
The attenuation law says the beam is fully stopped after a finite thickness.
False. An exponential never reaches zero; it only gets arbitrarily small. There is always a residual (tiny) transmitted intensity, which is why shielding is specified by an attenuation factor, not a "stopping distance."
If and you supply exactly of projectile kinetic energy, the reaction proceeds.
False. Momentum conservation forces the products to keep drifting forward, locking up some energy as centre-of-mass motion; you need (Picture 2).
A charged projectile with energy below the classical Coulomb barrier cannot cause any reaction.
False. Quantum tunnelling lets the cross-section stay small but nonzero below the barrier (Picture 3); this sub-barrier reaction rate is what powers fusion in stars.
Using atomic masses instead of nuclear masses gives the wrong Q-value.
False (if used consistently). For reactions that conserve total , the electron masses on both sides cancel, so consistent atomic masses give the correct ; the error only appears when you mix nuclear and atomic masses.
The mean free path gets longer when the material is denser.
False. Denser material means larger , hence larger , hence shorter mean free path — particles find targets sooner.
Spot the error
Each statement contains a flaw. Name it.
" because energy conservation says we're short by ."
The flaw is ignoring momentum: the products cannot be created at rest, so part of the input energy is unavailable, giving (the recoil tax of Picture 2).
"Since , a cross-section of b means the nucleus is about in physical size."
The number is an effective area from quantum resonance, not the geometric size; a real nucleus is roughly , so b vastly overstates its physical extent.
", released when reactants are more tightly bound."
The binding-energy formula is reversed: , and the reaction is exoergic when the products are more tightly bound (higher on the binding-energy curve of Picture 1).
"Because has units of area, the reaction rate is ."
Dimensionally and physically wrong: rate = area × incoming flux, so (a product), giving reactions per target per unit time.
"The macroscopic cross-section has units of barns."
multiplies (nuclei per volume) by (area), giving inverse length (); barns are the unit of the microscopic alone.
"In , a very heavy target wastes most of the beam energy on CM motion."
Reversed: for a heavy target , so almost all lab energy is available in the CM frame — a heavy target barely recoils and wastes the least, so .
"Because binding energy is a positive number, a nucleus with more binding energy per nucleon is less stable."
Higher binding energy per nucleon means the nucleus is held together more strongly, i.e. more stable; that is precisely why moving toward the peak of the curve releases energy.
Why questions
Explain the reasoning, not just the fact.
Why can fusion of light nuclei and fission of heavy nuclei both release energy?
Both processes move nucleons toward the peak of the binding-energy-per-nucleon curve (Picture 1), raising total binding energy, so .
Why do we use (see Mass defect & E=mc²) at all instead of just adding up chemical bond energies?
Nuclear rearrangements change rest mass measurably (fractions of a u), and that lost mass reappears as kinetic energy via — far larger than chemical energies, which involve negligible mass change.
Why must the threshold be computed with the centre-of-mass energy rather than the lab energy?
Only energy in the CM frame is free to be spent on rearranging nuclei; the CM's overall drift motion (fixed by momentum conservation) is untouchable, so the reaction "turns on" when (Picture 2).
Why does the fraction of usable energy equal and not something else?
The centre of mass is dragged forward by the projectile at ; the energy tied up in that forced drift is the fraction , so the remainder is what stays available — the target's "share" of the mass sets how little is wasted.
Why does a huge cross-section give a tiny half-thickness of absorber?
A large raises , and half-thickness shrinks as grows — so strongly-absorbing nuclei (like for neutrons) stop a beam in a very thin layer.
Why is the reaction rate written per target as but per sample as ?
Each nucleus independently presents area to flux , so one target reacts at rate ; with identical independent targets the rates simply add, giving .
Why does the rate depend on the flux (density times speed) and not on alone?
only tells you how big one target looks; the rate also needs how many projectiles actually arrive per second per area, and that arrival count is (how densely packed the projectiles are, ) times (how fast they sweep past, ) — so both a denser and a faster beam deliver more hits even though is unchanged. See Neutron flux & reactor physics.
Why can neutrons often react at very low energies while charged 's cannot?
Neutrons feel no Coulomb repulsion, so even slow (thermal) neutrons reach the nucleus, while charged projectiles must first climb — or quantum-tunnel through — the Coulomb barrier (Picture 3), an energy hurdle separate from or .
Why does the attenuation follow an exponential rather than a straight-line decrease?
Each thin slice removes a fixed fraction of whatever intensity remains, and "constant fractional loss per step" integrates to an exponential — the same logic as radioactive decay.
Edge cases
The scenarios that break naive formulas — say what actually happens.
What is for a reaction with ?
The formula gives a negative number, which we read as "no threshold": an exoergic reaction has no minimum kinetic energy requirement (a neutral projectile can react even at rest-like energies).
What happens to as the target mass becomes enormous compared to ?
The factor , so : with a heavy, essentially immovable target almost no energy is lost to recoil, and you need barely more than .
What does a charged projectile's cross-section do just below the classical Coulomb barrier?
It does not snap to zero — quantum tunnelling keeps it small but finite (Picture 3), which is why sub-barrier fusion in stars proceeds at all.
What does an endoergic channel's cross-section do below its reaction threshold ?
That channel's is zero (the reaction is energetically forbidden), so no matter how intense the beam, the product never forms until is reached.
If the projectile energy is exactly at a resonance peak, what happens to and the mean free path?
spikes (possibly thousands of barns), so is large and the mean free path becomes very short — the beam is absorbed almost immediately.
What is the Q-value of a reaction where reactants and products have identical total rest mass?
: no mass converts to kinetic energy, so the reaction neither releases nor absorbs energy and behaves like an elastic rearrangement.
In the limit (vacuum, no target nuclei), what does predict?
so : with nothing to hit, the beam passes through undiminished — the formula correctly reduces to "no attenuation."
Recall One-line summaries to carry away
- is frame-independent; threshold and energy-sharing are not.
- measures probability, never physical size — and can be nonzero below the classical barrier via tunnelling.
- Exponential attenuation never fully stops a beam.
- Momentum, not just energy, sets ; the extra factor is the recoil tax.