1.1.8 · D5Matter, Measurement & the Mole
Question bank — Law of conservation of mass (Lavoisier) — proof, examples


True or false — justify
Mass is always conserved in every chemical reaction, no matter the container.
False — the universe's mass is conserved, but a container only shows it when it is closed; an open flask can lose gas and appear lighter.
If a balanced equation has equal atom counts on both sides, mass is automatically conserved.
True — equal atom counts of each element times fixed atomic masses give equal total mass, so balancing is conservation at the atomic level.
When wood burns to ash weighing less than the wood, some mass was destroyed.
False — the missing mass left as and water vapour; trap those gases in a sealed box and the mass is unchanged.
In a sealed candle-in-a-jar experiment the jar+contents have less mass after the candle burns out.
False — the wax's carbon and hydrogen became and still trapped inside; total sealed mass is identical.
Conservation of mass holds exactly in nuclear reactions too.
False — nuclei change identity and a tiny mass defect converts to energy via ; here is mass and the speed of light. See Mass–Energy Equivalence (E=mc²), which shows why that mass change is measurable only for nuclei, not chemical bonds.
Lavoisier's law depends on knowing the chemical formulas of the substances.
False — it only needs atoms to be conserved (Dalton's postulate: atoms are indestructible); you can verify it by weighing alone, without any formula.
A rusting iron nail in open air gains mass.
True — iron combines with oxygen from the air to form iron oxide, so the solid pulls mass in from an open surroundings.
If you weigh only the solid products of an open reaction, that total equals the reactant mass.
False — any gas released or absorbed is left out; you must count entering/escaping gas to recover .
Dissolving salt in water in a sealed jar changes the jar's total mass.
False — dissolving is a physical change; atoms are merely dispersed, none created or destroyed, so mass is unchanged. This rests on Dalton's picture of indestructible atoms (Dalton's Atomic Theory).
Spot the error
" of heated openly leaves of , therefore of mass vanished."
The error is calling the system closed; the escaped as gas, so is still conserved.
" can give any mass of water depending on conditions."
The error ignores atom conservation; all reactant atoms end up in the product, so the water mass is fixed at exactly .
"Balancing an equation is just a formatting rule with no physical meaning."
The error misses that balancing enforces equal atom counts per element, which is literally conservation of mass. That equal-counts bookkeeping is the whole job of Balancing Chemical Equations.
"Lavoisier's sealed-retort trick worked because mercury does not react, so nothing changed."
The error is backwards — mercury does react. In a sealed glass retort he heated liquid mercury in a fixed pocket of air; over days the surface grew a red crust of mercury(II) oxide, . The solid gained exactly the mass the sealed air's oxygen lost, so the whole apparatus weighed the same before and after. The timeline figure lays this out step by step.
"Since a burning candle shrinks, mass depends on how much solid you can see."
The error is trusting the eye, which tracks only solids/liquids; the lost solid became invisible gas of equal mass.
"Mass conservation fails for photosynthesis because a tiny tree becomes a huge tree."
The error ignores mass drawn in from and water; the tree's added mass comes from the surroundings, not from nothing.
" means chemical reactions also lose weighable mass."
The error applies a nuclear-scale effect to chemistry; in chemical bonds the energy change is so small the corresponding mass change is far below any balance's sensitivity.

Why questions
Why must Lavoisier's vessel be sealed for the experiment to prove the law?
Sealing keeps the system closed so no gas can enter or leave, meaning any mass rearranged internally still shows up on the same balance.
Why does the law follow logically from Dalton's atomic theory rather than needing separate proof?
If atoms are neither created nor destroyed and each has a fixed mass, the total (atom count times atomic mass , summed over elements) cannot change when only bonds rearrange.
Why do open-air combustion experiments seem to violate the law even though they do not?
Gaseous products escape uncounted, so the container loses mass while the atoms are simply relocated into the surrounding air.
Why is "atom counts conserved per element" a stronger statement than "total mass conserved"?
Equal per-element counts guarantee equal total mass, but also forbid one element turning into another — it is conservation at the finer, atomic level, and this is the bedrock that lets Stoichiometry and the Mole predict exact amounts.
Why can you find one unknown reactant mass by subtraction in a closed system?
Because is a single equation; if all masses but one are known, algebra pins the last one exactly.
Why does the law connect naturally to the Law of Definite Proportions?
Both stem from fixed atomic masses combining in whole-number ratios, so mass is conserved and distributed in constant proportions (a fixed compound always has the same element-by-element mass split).
Why is it wrong to say "matter is destroyed" but acceptable to say "the solid disappeared"?
The solid genuinely transformed into gas (a real disappearance of that phase), but the matter itself persists, so "destroyed" overclaims.
Edge cases
A reaction produces zero gas and consumes zero gas (all solids/liquids). Does an open container conserve mass on the balance?
Yes — with no gas crossing the boundary, an open container behaves like a closed one and the balance reads constant.
Two gases react to form a liquid inside a sealed rigid jar; does the jar's mass drop as pressure falls?
No — pressure change does not remove atoms; the same atoms are inside, now as liquid, so the total mass is unchanged.
A sealed flask holds a reaction that releases heat to the room. Does losing energy lose weighable mass?
Not measurably — chemical energy release corresponds to a mass change so minuscule () that no laboratory balance can detect it.
Uranium in a sealed container undergoes fission. Is the classical law obeyed?
No — nuclei split and a real mass defect converts to energy, so this is a nuclear regime where Mass–Energy Equivalence (E=mc²) (mass turning into energy) replaces the strict chemical law.
An electrolysis cell splits water into and gas, both allowed to bubble out of an open beaker. What happens to the beaker's mass?
It falls, because the gases carry their mass out; seal the cell and collect the gases and the total is conserved.
A sealed jar of reactants is left untouched — no reaction occurs. Is the law "on" or "off"?
It is trivially satisfied; with no change at all, reactant mass equals product mass because they are literally the same matter.
Photosynthesis in a sealed terrarium: total mass over a week?
Unchanged — carbon moves from into plant tissue and oxygen is released, but all atoms stay inside the sealed boundary.
Connections
- Dalton's Atomic Theory — the indestructible-atom postulate every trap secretly relies on.
- Balancing Chemical Equations — the practical proof that atoms (and mass) are conserved.
- Law of Definite Proportions — the sibling mass law built on the same fixed atomic masses.
- Stoichiometry and the Mole — turns conservation into quantitative predictions.
- Mass–Energy Equivalence (E=mc²) — the one regime where the classical answer flips.