4.3.11 · D1Semiconductor Fabrication

Foundations — Ion implantation and diffusion

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This page builds every symbol the parent Ion Implantation and Diffusion note uses, starting from a smart 12-year-old who has never seen any of them. Read top to bottom; each block earns the next.


0. The stage: a wafer and a depth axis

Before any symbol, fix the picture in your head. A wafer is a thin flat disc of silicon. We only ever care about how things change going straight down into it. So we draw one axis:

  • = depth below the surface, in centimetres. is the top surface; larger = deeper inside.

That single axis is the backbone of every formula on the parent page.

Figure — Ion implantation and diffusion

1. Counting atoms: concentration and dose

Now we need two different ways to count dopant atoms. They are not the same and confusing them is the #1 beginner error.

The bridge between them is the key relationship you will meet again and again:

Figure — Ion implantation and diffusion

Link forward: doses and profiles are what Doping and PN Junctions turns into working device regions.


2. Flux — the flow of atoms

To describe movement we need one more counter.

Why we need it: diffusion is a story about atoms crossing planes, so we need a word for that crossing rate. is that word.


3. Slope of a curve: the derivative

The parent note says flux is driven by how steep the concentration is. "Steepness" is a derivative — so let us earn that symbol from zero.

Why the curly instead of a plain ? Because depends on two things at once — depth and time . The symbol means "slope in the direction, holding time frozen." That is a partial derivative. (More in Diffusion Equation.)

  • If falls as we go deeper (typical: crowded at surface, clean below), the slope is negative.
  • A steep fall = large-magnitude slope = strong driving force for diffusion.
Figure — Ion implantation and diffusion

4. The diffusion coefficient — "how fast atoms wander"

Why cm²/s and not cm/s? Because diffusion spreads like (area-like, not distance-like). Hold that thought — it is the deepest fact on the parent page. See Fick's Laws.


5. Temperature , energy barrier , and the Arrhenius factor

depends violently on temperature. To see why, meet three symbols.

Now the Arrhenius factor reads in plain words: the fraction of atoms lucky enough to have more than the barrier energy .

Figure — Ion implantation and diffusion

Here is just the "maximum possible" diffusion rate (the value if the barrier vanished) — the prefactor the exponential scales down.


6. The bell curve: the Gaussian and the error function

Both ion-implant profiles and drive-in diffusion end up shaped like a bell curve (Gaussian). Two symbols describe it.

A Gaussian says: concentration is highest () right at the centre , and drops off smoothly and symmetrically on both sides, the drop-off scale set by .

Why these and not something simpler? Because they are the exact answers to the diffusion equation for the two source conditions — nothing simpler solves it. Details in Diffusion Equation and Fick's Laws.


7. Beam symbols for implantation

Ion implantation counts atoms electrically, so it borrows three circuit symbols.


8. How it all feeds the topic

depth x - the axis

concentration N per volume

dose Q per area = area under N

slope dN dx - the driving force

flux J - atoms crossing a plane

diffusion coefficient D

temperature T

Arrhenius factor

barrier Ea

Boltzmann k

Fick first law

Fick second law - diffusion equation

second derivative - curvature

erfc and Gaussian profiles

range Rp and straggle

implant Gaussian

beam current I and time t

dose from charge

Ion implantation and diffusion

Related builds: Thermal Oxidation, Photolithography, and MOSFET Structure all reuse these same counting and depth ideas within Semiconductor Fabrication.


Equipment checklist

Cover the right side and answer each — if any stumps you, re-read that section.

What does measure and where is ?
Depth below the wafer surface; is the top surface.
Difference between and (with units)?
= atoms per volume (cm⁻³) at a depth; = atoms per area (cm⁻²), the total down a column. .
What is flux and what does positive mean?
Atoms crossing a plane per cm² per second; positive = net flow deeper (increasing ).
What does represent as a picture?
The slope (steepness) of the concentration-vs-depth curve at fixed time.
Why the curly instead of ?
depends on both and ; means slope in with time held fixed (partial derivative).
What does the second derivative measure?
Curvature — how the slope changes with depth; drives pile-up/drain in Fick's 2nd law.
What is and its units, and why cm²/s?
Diffusion coefficient — how easily atoms wander; cm²/s because spreading scales as (area-like).
In words, what is ?
The fraction of atoms with enough thermal energy to clear the hopping barrier .
What do and mean geometrically?
= centre (average stop depth) of the implant bell; = its half-width (standard deviation).
What does look like as grows?
Falls smoothly from 1 (at surface) to 0 (deep) — the constant-source diffusion shape.
How does implantation get exact dose from a beam?
: count total charge , divide by charge per ion and area .