5.4.1 · D3Materials Chemistry (Aerospace)

Worked examples — Metals & alloys — Al alloys (2024, 7075), Ti alloys (Ti-6Al-4V), Ni superalloys (Inconel, Hastelloy), stainless steels

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This page is the drill hall for the parent topic. The parent gave you the rules; here we run the rules across every kind of question the topic can throw at you — and we prove each number.

Before any formula appears, one promise: every symbol used below is defined the first time it shows up. If your eyes glaze at "", relax — we build it from "strength divided by heaviness."


The scenario matrix

Think of this topic as a machine with a few "dials." Each cell below is one setting of the dials. Our worked examples must land on every cell.

# Cell (case class) What makes it distinct Covered by
A Ranking by specific strength divide, compare ratios Ex 1
B Zero / degenerate input pure metal, no strengthening (, ) Ex 2
C Limiting value grain size , precipitate spacing Ex 3
D Hall–Petch two-point solve back out constants from data Ex 4
E Orowan precipitate spacing , tiny units (nm) Ex 5
F Real-world word problem choose a family from a spec Ex 6
G The "flip" case (temperature reverses the rule) small grains help cold, hurt hot Ex 7
H Exam twist / trap "stronger = better?" toughness trade-off Ex 8
I Unit-conversion landmine MPa, g/cm³, SI mixups Ex 9

Ex 1 — Cell A: Rank three metals by specific strength

Forecast: which wins — the strongest (steel) or the lightest (Al)? Guess before reading.

  1. Compute each ratio .
    • Why this step? A wing spar carries load while being flown, so we score strength per unit mass, not raw strength.
  2. Order the numbers, largest first.
    • Why this step? Larger = more strength you keep for every kilogram you're forced to fly.

Verify: the steel is strongest in absolute MPa (1000 > 880 > 500) yet loses on the scoreboard — exactly the parent's claim that "titanium often beats steel even though steel is stronger." Units: is consistent across all three, so the comparison is fair. See Precipitation Hardening for why 17-4PH reaches 1000 MPa at all.

Figure — Metals & alloys — Al alloys (2024, 7075), Ti alloys (Ti-6Al-4V), Ni superalloys (Inconel, Hastelloy), stainless steels

Ex 2 — Cell B: Degenerate input (pure metal, no obstacles)

Recall the parent's law:

Forecast: with the grain "infinitely big," should the added strength be large or nearly zero?

  1. Take the limit .
    • Why this step? "No obstacles" literally means grain walls are so far apart a dislocation never meets one — Dislocations and Slip glide freely.
  2. Substitute.
    • Why this step? The boundary term vanishes, leaving only the base stress.

Verify: a pure metal is weak — 20 MPa is tiny next to Ex 1's alloys (500 MPa). This is the degenerate floor of the formula: strip every strengthener and you fall back to . Sanity check on units: has . ✓


Ex 3 — Cell C: Limiting value (grains shrink toward zero)

Forecast: does strength climb without limit, or level off?

  1. Convert each grain size to metres.
    • Why this step? is in , so must be in metres or the units lie.
  2. Evaluate .
    • Why this step? Direct application; smaller → larger → more strength.
  3. Read the trend .
    • Why this step? , so the formula says — but physically grains can't shrink below a few atoms, so real strength saturates. The maths gives an idealized limit; the world caps it.

Verify: each 10× shrink in multiplies the boundary term by (100→316→1000). Strengths rise 27 → 42.1 → 90 MPa, monotonically — matching Hall–Petch Strengthening: "smaller grains → stronger."

Figure — Metals & alloys — Al alloys (2024, 7075), Ti alloys (Ti-6Al-4V), Ni superalloys (Inconel, Hastelloy), stainless steels

Ex 4 — Cell D: Solve for the constants from two data points

Forecast: Hall–Petch is a straight line in the variable . Two points → one line → unique .

  1. Build for each point (metres!).
    • Why this step? Plotting against turns the curve into a line .
  2. Slope = rise/run.
    • Why this step? On a line, the slope is the constant ; it's the "strength gained per unit ."
  3. Intercept = plug one point back.
    • Why this step? Knowing , the base stress falls straight out of .

Verify: test the other point: MPa ✓. Both points sit on the line, so the fit is exact.


Ex 5 — Cell E: Orowan spacing from precipitate strengthening

Recall:

Forecast: for a strong alloy do we expect in microns or nanometres?

  1. Rearrange for .
    • Why this step? We know the strengthening we want and solve for the microstructure that delivers it.
  2. Match units — convert to metres, to Pa.
    • Why this step? Mixing nm with MPa gives nonsense; SI keeps it honest.
  3. Compute.

Verify: nm — nanometre-scale, exactly the "fine second-phase particles" the parent describes for peak-aged tempers. If we halved to 39 nm, would double to 200 MPa (inverse law) ✓.


Ex 6 — Cell F: Real-world word problem (choose the family)

Forecast: temperature is the loudest constraint — which family alone survives ~1000 °C?

  1. List max service temperatures (parent table).
    • Why this step? Any material failing the temperature is disqualified before we even weigh it.
  2. Eliminate by temperature.
    • Why this step? 950 °C exceeds Al, Ti, and stainless limits; only Ni superalloy remains.
  3. Confirm the extra specs.
    • Why this step? A survivor must also match (b): creep resistance via γ′ precipitates and oxidation resistance via Cr — both are Inconel's specialty.

Answer: Nickel superalloy (Inconel-type). Weight being secondary is exactly why its high density () is tolerable here.

Verify: cross-check the mnemonic ladder "All Tigers Snore Nightly" — the hottest rung is Ni. Only Ni clears 950 °C, so the choice is forced, not preferred. ✓


Ex 7 — Cell G: The temperature "flip" (small grains help, then hurt)

Forecast: how can "add boundaries" and "remove all boundaries" both be right?

  1. Cold regime: boundaries are obstacles.
    • Why this step? At low T, dislocation glide dominates; each boundary blocks slip → Hall–Petch rewards small . (Hall–Petch Strengthening.)
  2. Hot regime: boundaries are highways for failure.
    • Why this step? Above ~0.7× melting T, atoms diffuse and grains slide past each other; boundaries crack via creep. More boundary length = more places to fail.
  3. Take the limit that kills creep.
    • Why this step? Setting (one crystal) removes every sliding surface → single-crystal blades.

Verify: both obey physics of their regime — the rule didn't break, the dominant deformation mode changed from slip (cold) to creep (hot). This is the parent's "strengthening rules flip with temperature." The Hall–Petch term simply becomes irrelevant when the failure mechanism is no longer dislocation slip.

Figure — Metals & alloys — Al alloys (2024, 7075), Ti alloys (Ti-6Al-4V), Ni superalloys (Inconel, Hastelloy), stainless steels

Ex 8 — Cell H: Exam trap ("stronger is always better")

Forecast: does the number 500 > 350 settle it?

  1. Identify the governing failure mode.
    • Why this step? A lower fuselage skin is damage-tolerant / fatigue-driven, so the metric is fracture toughness, not peak yield.
  2. Compare on the right metric.
    • Why this step? 7075 has higher yield but lower fracture toughness and worse stress-corrosion resistance; 2024 tolerates cracks longer before catastrophic failure.
  3. Match load to family (parent's rule).
    • Why this step? Compression-loaded upper wing → 7075; fatigue-critical lower fuselage → 2024.

Answer: The reasoning is wrong. Correct pick is 2024-T3.

Verify: compute specific strengths — vs . 7075 does win on , confirming the trap is seductive, yet the failure mode, not , decides here. Right tool, right load.


Ex 9 — Cell I: Unit-conversion landmine

Forecast: same physics — why two different numbers?

  1. Write out each with units.
    • Why this step? A ratio is meaningless without its units; the "0.199" and "198.6" differ only by the density's unit.
  2. Show they're the SAME quantity.
    • Why this step? , so dividing by a number 1000× larger gives a result 1000× smaller: .
  3. Pick the engineering convention.
    • Why this step? Aerospace tables (parent table) quote with in g/cm³, giving the familiar "~200."

Verify: ✓. Both classmates are right — they just reported different units. This matches the parent's "" for Ti-6Al-4V.


Recall Quick self-test (reveal after guessing)

Which cell does "pure iron, no alloying, " belong to? ::: Cell B (degenerate input) — . Ti vs steel by specific strength — who wins and why? ::: Ti (~199 vs ~127); strength-per-mass favours the lighter metal even though steel is stronger absolutely. Why single-crystal blades, if boundaries make metals strong? ::: Cell G flip — at >0.7 T_melt boundaries slide/crack via creep, so removing them () is stronger hot. Lower fuselage skin: 2024 or 7075, and why? ::: 2024 — fatigue/damage-tolerant, higher fracture toughness; yield strength is the wrong metric there.