5.2.8 · Chemistry › Nuclear & Radiochemistry
Radioactive nuclei ek reliable kaam karte hain: woh ek fixed probabilistic rate se decay karte hain jo half-life t 1/2 se set hoti hai. Humans ise teen tarike se use karte hain:
Clock — count karo kitna decay hua hai → time batao (radiocarbon dating).
Tracer/Beam — emit hoti radiation batati hai kahaan (Tc-99m imaging) ya tissue ko destroy karti hai (I-131 therapy).
Battery — decay heat → electricity (RTG, Pu-238 spacecraft).
Neeche sab kuch wohi exponential decay law hai jo alag-alag kaam ke liye dress up hua hai.
Definition Radioactive decay law
Un-decayed nuclei N ki sankhya itni girti hai ki decay ki rate itni hi hoti hai jitne baaki bache hain :
d t d N = − λ N
λ = decay constant (probability per nucleus per unit time).
Intuition Yeh kaam kyun karta hai
Cosmic rays upper atmosphere se takraate hain → neutrons banate hain → woh neutrons nitrogen ko radioactive carbon-14 mein convert karte hain:
7 14 N + 0 1 n → 6 14 C + 1 1 p
Jeevit cheezein lagaatar carbon khaati/saansti hain, isliye unka 14 C / 12 C ratio atmosphere se match karta hai (constant rehta hai). Marne par, intake ruk jaata hai — clock shuru hoti hai. 14 C wapas decay karta hai:
6 14 C → 7 14 N + − 1 0 β
t 1/2 = 5730 yr ke saath. Measure karo ki sample kitna depleted hai → age pata chale.
Worked example Ek wooden idol 11.6 counts/min/g deta hai; fresh wood 15.3 counts/min/g deta hai. Age?
Step 1 — λ = ln 2/5730 = 1.21 × 1 0 − 4 yr − 1 . Kyun? Time mein ratio convert karne ke liye λ chahiye.
Step 2 — ratio A 0 / A = 15.3/11.6 = 1.319 . Kyun? Yahi depletion factor hai.
Step 3 — t = 1.21 × 1 0 − 4 1 ln ( 1.319 ) = 1.21 × 1 0 − 4 0.277 ≈ 2290 yr .
Yeh step kyun? Exponential ko invert karne se marne ke baad beeta hua time milta hai.
Worked example Kitne half-lives baad sirf 25%
14 C bachega?
0.25 = ( 1/2 ) n ⇒ n = 2 , isliye t = 2 × 5730 = 11460 yr. Kyun? Har half-life amount ko aadha kar deti hai; 25% = do halvings.
Common mistake "Radiocarbon dinosaur bones (65 Myr) ko date kar sakta hai."
Kyun sahi lagta hai: carbon sab life mein hota hai, toh ise har jagah kyun nahi use karein?
Fix: ~10 half-lives (~57,000 yr) ke baad itna kam 14 C bachta hai ki woh measure hi nahi hota. Purane fossils ko long-lived clocks chahiye jaise ==U-238 (t 1/2 = 4.5 Gyr)== ya K-40.
"m" = metastable (ek excited nuclear state). Yeh ek clean gamma photon (140 keV) emit karke relax karta hai — gamma camera ke liye perfect energy — t 1/2 = 6 h ke saath.
99 m Tc → 99 Tc + γ ( 140 keV )
Worked example 6 h "just right" kyun hai
Bahut chhota (minutes): scan se pehle decay ho jaata hai; bahut lamba (days): patient dinon tak irradiated rehta hai. 6 h ⇒ ek-din ke scan ke baad (≈ 4 half-lives) sirf ( 1/2 ) 4 = 1/16 ≈ 6% activity bachti hai. Yeh step kyun? Dikhata hai ki dose jaldi self-limit ho jaata hai.
Ek ==destructive β − particle== emit karta hai (plus kuch γ ), t 1/2 = 8 days:
53 131 I → 54 131 Xe + − 1 0 β + ν ˉ
Intuition Iodine thyroid ko kyun target karta hai
Thyroid gland naturally iodine concentrate karti hai hormones banane ke liye. Radioactive iodine do → yeh thyroid mein jaata hai → short-range β − overactive ya cancerous thyroid cells ko locally maarta hai bina baki body ko jalaye. Biology targeting ka kaam free mein kar deti hai.
Common mistake "Therapy ke liye bhi
γ -only emitter use karo."
Kyun sahi lagta hai: γ hi woh radiation hai jo hum hamesha sunते hain.
Fix: γ tissue se guzar jaati hai aur bahut kam energy deposit karti hai — imaging ke liye badhiya, maarne ke liye bekar. Therapy ko α / β chahiye jo apni saari energy ek tiny range mein dump kar dein. Diagnosis = penetrating γ ; Therapy = short-range β / α .
Intuition Solar panels kyun nahi?
Voyager, Cassini, New Horizons wahaan udte hain jahan sunlight bahut weak hai. Unhe decades tak steady power chahiye bina kisi moving parts ke aur bina sunlight ke . Solution: ek Radioisotope Thermoelectric Generator (RTG) .
Definition RTG kaise kaam karta hai
Pu-238 α decay karta hai, t 1/2 = 87.7 yr:
94 238 Pu → 92 234 U + 2 4 α + heat
α particles turant rok liye jaate hain → kinetic energy heat ban jaati hai (~0.56 W per gram).
Thermocouples (Seebeck effect) temperature difference (hot Pu vs cold space) ko seedha electricity mein convert karte hain.
Intuition Specifically Pu-238 kyun?
α emitter → decay per bahut zyada energy, lekin α kagaz ki sheet se rok liya jaata hai ⇒ easy shielding, safe-ish.
87.7 yr half-life → power decades tak chalti hai (Voyager 1977 mein launch hua abhi bhi chal raha hai!).
Pu-239 nahi (woh bomb/reactor isotope hai) — bilkul alag kaam.
Worked example 35 saal baad probe par kitni power bachegi?
λ = ln 2/87.7 = 7.90 × 1 0 − 3 yr − 1 .
Fraction = e − λ t = e − 0.2766 = 0.758 , isliye original thermal power ka ~76% . Yeh step kyun? Heat output ∝ decay rate ∝ N , isliye yeh usi e − λ t follow karta hai — yahi wajah hai ki RTGs dheere-dheere dim hote hain lekin achanak kabhi nahi mrtey.
Use
Isotope
Radiation
t 1/2
Kyun choose kiya
Dating
C-14
β −
5730 yr
organics ki age range se match karta hai
Imaging
Tc-99m
γ (140 keV)
6 h
bahar penetrate karta hai, low dose
Therapy
I-131
β −
8 d
thyroid-seeking, locally maarta hai
Power
Pu-238
α
87.7 yr
dense heat, decades ki life
Recall Feynman: 12-saal ke bachche ko samjhao
Radioactive atoms aise hain jaise ice cubes jo ek set speed se pighalni hain. Dating: pata karo ki ek purana cube kitna pighal chuka hai taaki pata chale woh freezer se kitni der pehle nikala gaya. Tc-99m: ek cube jo quietly glow karta hai taaki ek camera tumhare andar ise dhundh sake, phir jaldi pighal jaata hai taaki hurt na kare. I-131: ek cube jo tumhare throat-gland mein baith jaata hai aur paas ki buri cells ko "jalata" hai. Pu-238: ek cube jo 90 saal tak warm rehta hai, aur hum us warmth ko electricity mein convert karte hain Sun se door ek spaceship chalane ke liye.
Mnemonic Isotope ko kaam se match karo
"Carbon Counts, Tc Takes-pictures, Iodine Incinerates, Plutonium Powers."
Radiation type rule: "See it = γ , Slay it = β / α ."
Radiocarbon dating mein "counting" sirf death par kyun shuru hoti hai? Jeevit cheezein atmosphere se 14 C replenish karti rehti hain; death par intake ruk jaata hai isliye fixed-rate decay ek clock ban jaati hai.
Woh nuclear reaction jo atmosphere mein C-14 banati hai? 7 14 N + 0 1 n → 6 14 C + 1 1 p
Activities se age formula? t = λ 1 ln ( A 0 / A ) = l n 2 t 1/2 ln ( A 0 / A )
C-14 dinosaurs ko date kyun nahi kar sakta? ~10 half-lives (~57,000 yr) ke baad almost koi 14 C nahi bachta; iske badle long-lived U-238/K-40 chahiye.
Tc-99m mein "m" ka matlab kya hai? Metastable — ek excited nuclear isomer jo 140 keV gamma emit karke decay karta hai.
Imaging ke liye Tc-99m ideal kyun hai (3 wajah)? Pure penetrating γ (detectable, low dose), 6 h half-life (scan phir clear ho jaata hai), Mo-99 se on-site generator-produced.
Woh parent isotope jisse Tc-99m generator "milka" jaata hai? Mo-99 (t 1/2 = 66 h).
I-131 specifically thyroid ko kyun treat karta hai? Thyroid naturally iodine concentrate karti hai, isliye I-131 self-target karta hai; iska short-range β − cells ko locally maarta hai.
Imaging vs therapy radiation rule? Imaging ko penetrating γ chahiye (detector tak jaata hai, low damage); therapy ko short-range β / α chahiye (cells maarne ke liye locally saari energy deposit karta hai).
RTG mein Pu-238 ka decay? 94 238 Pu → 92 234 U + 2 4 α + heat , t 1/2 = 87.7 yr.
RTG decay ko electricity mein kaise convert karta hai? α particles ruk jaate hain aur heat produce karte hain; thermocouples (Seebeck effect) hot–cold temperature difference ko electricity mein convert karte hain.
Spacecraft ke liye Pu-238, Pu-239 kyun nahi? Pu-238 ek long-lived (87.7 yr) α emitter hai jisme dense, easily-shielded heat hai; Pu-239 fissile bomb/reactor isotope hai.
t 1/2 = ln 2/ λ derive karo.N = N 0 e − λ t mein N = N 0 /2 set karo: 1/2 = e − λ t 1/2 ⇒ ln 2 = λ t 1/2 .
Radioactive Decay Law — N = N 0 e − λ t engine jo in sab ke peeche hai.
Half-life and Decay Constant — kyun har isotope ka t 1/2 uske kaam ke liye fit hai.
Types of Radioactive Decay (alpha, beta, gamma) — penetration decide karti hai diagnose karo ya treat karo.
Nuclear Reactions and Transmutation — C-14 aur Pu-238 kaise produce hote hain.
Seebeck Effect / Thermocouples — RTG converter ki physics.
Activity and Units (Becquerel, Curie) — dating mein hum actually kya measure karte hain.
radiation location or damage
Decay law dN/dt = -lambda N
t = ln A0 over A divided by lambda