5.2.4 · D5Nuclear & Radiochemistry

Question bank — Radioactive series — uranium, thorium, actinium

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True or false — justify

Every member of one radioactive series has the same .
True. An decay changes by exactly (remainder unchanged) and a decay changes by , so the remainder is frozen for the whole chain — that is what defines the family.
A decay changes the mass number of the nucleus.
False. The emitted electron comes from a neutron turning into a proton; the total count of nucleons stays the same, so is unchanged (only rises by 1).
Since there are four possible values of , all four series are found abundantly in nature.
False. There are four mathematically possible families, but the (neptunium) series has no long-lived member, so it has fully decayed away and is essentially absent naturally.
The uranium and actinium series both start from a uranium isotope.
True. Uranium series starts at () and actinium series starts at (); same element , different mass numbers put them in different families.
All natural radioactive series end on an isotope of lead.
False. Three end on lead (), but the neptunium series ends on bismuth, — a different element entirely.
If two nuclides have the same , they must belong to the same series.
False. Sharing is necessary but not sufficient; they also need to lie on the same actual decay chain. A nuclide from an unrelated chain can share the remainder without being connected.
survives on Earth today because its half-life is comparable to the planet's age.
True. With yr (about the age of the Earth), only roughly half of the original has decayed, so plenty remains to be found.

Spot the error

"To count betas, just do because each beta raises by one."
Error: this ignores the alphas, which each lower by 2. The correct relation is ; the term undoes the alpha contribution before reading off the betas.
" reaches lead in a single, very energetic alpha decay."
Error: one drops by only 4 (to 234), not by the 32 needed. Reaching requires a whole staircase of 8 alphas and 6 betas — no single decay can span that gap.
"The neptunium series is missing because neptunium was never made in the first place."
Error: it was present when the Earth formed; it is missing now because its longest-lived member (, yr) is far shorter-lived than the Earth's age, so it has decayed to undetectable amounts.
"A series is labelled , so its parent must have mass number exactly 2."
Error: is a (large) integer, not zero. For the uranium series , so ; the label only fixes the remainder , not itself.
"Every alpha decay is followed by a beta decay, one for one."
Error: the counts are independent. In the uranium series there are 8 alphas but only 6 betas; the numbers are set separately by the mass-number and atomic-number balances, not by pairing.
"The series ends on lead like the others, just a rarer isotope."
Error: its endpoint has . Lead's stable isotopes are (remainders ); none give remainder 1, so the endpoint is instead.

Why questions

Why is — and not or — the conserved label?
Because the two decays' effects on are " or ", both multiples of 4, so remainder mod 4 is untouched. changes by or (no clean invariant), and would merge families that alphas can never mix.
Why must a heavy nucleus like decay through a chain rather than one step?
It must shed roughly 32 mass units and rebalance its proton count; a single decay changes by at most 4, so many sequential steps are the only way down to a stable configuration (Nuclear stability and band of stability).
Why does emitting an alpha lower while emitting a beta raises it?
An carries away 2 protons ( drops by 2); a converts a neutron into a proton inside the nucleus and ejects an electron, so the proton count rises by 1 (Alpha decay, Beta decay).
Why do we compute the alpha count before the beta count ?
The beta formula needs as an input to cancel the alphas' effect on ; without knowing first, the term can't be evaluated.
Why can two of the four series be distinguished only by their endpoint's mass number?
Because their parents share element (both uranium) but differ in ; the family is then read off from the stable endpoint — () versus () — where shows the difference.
Why does the survival of a series in nature depend on its longest-lived member, not its parent alone?
If any bottleneck nuclide in the chain is long-lived it can hold the series "in stock"; but for these series the parent is the longest-lived member, so its half-life alone decides whether the whole chain persists (Half-life and decay constant).

Edge cases

Can a decay chain ever increase the mass number at some step?
No. The only two moves are ( drops by 4) and ( unchanged); neither can raise , so a chain marches monotonically downward or holds steady.
What is the smallest possible number of alpha decays in a chain, and when does it happen?
Zero — if parent and product have the same mass number (), then and the change is achieved by beta decay(s) alone, since only betas leave fixed.
If a chain produces a fractional alpha count from , what does that tell you?
That the two nuclides do not lie on the same series: must be a multiple of 4 for a real chain, so a non-integer means the parent and product have different and cannot be connected.
Is it possible for the beta count to come out negative?
In principle would signal / electron-capture behaviour instead of ; for the natural heavy series it never happens, because the alphas always overshoot downward and betas must climb it back up ().
What would it mean for the "" in to be zero or negative?
For real nuclei is a large positive integer, so is large and positive; or negative has no physical nucleus — the label only ever uses big enough to make match an actual mass number.
Could a stable endpoint ever be reached that is not lead or bismuth?
For these four specific series, no — the valley of stability at high funnels each family to or . The remainder pins which endpoint, and only those four nuclides are simultaneously stable and reachable (Radioactive dating relies on exactly this fixed endpoint).

Connections

  • Alpha decay — the single move that changes (by ); the reason is an invariant.
  • Beta decay — raises by 1 at fixed ; the source of the correction term.
  • Half-life and decay constant — decides which series survive on Earth and which vanish.
  • Group displacement law (Soddy–Fajans) — the per-step -shift bookkeeping behind every trap here.
  • Nuclear stability and band of stability — why heavy nuclei must shed mass through a chain at all.