5.4.1 · HinglishMaterials Chemistry (Aerospace)

Metals & alloys — Al alloys (2024, 7075), Ti alloys (Ti-6Al-4V), Ni superalloys (Inconel, Hastelloy), stainless steels

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5.4.1 · Chemistry › Materials Chemistry (Aerospace)


1. Master variable: Specific strength

Family ρ (g/cm³) Typical σ_y (MPa) σ_y/ρ Max service T
Al 2024/7075 ~2.8 350–500 ~150 ~150 °C
Ti-6Al-4V ~4.43 ~880 ~200 ~400 °C
Ni superalloy ~8.2 ~1000 (hot) ~120 ~1000+ °C
Stainless steel ~7.9 ~250–1000 ~50–125 ~600 °C

2. Alloys pure metals se zyada strong kyun hote hain (first principles)

Figure — Metals & alloys — Al alloys (2024, 7075), Ti alloys (Ti-6Al-4V), Ni superalloys (Inconel, Hastelloy), stainless steels

3. Charon families detail mein

3a. Aluminium alloys — 2024 & 7075

3b. Titanium — Ti-6Al-4V ("workhorse", α–β alloy)

3c. Nickel superalloys — Inconel, Hastelloy

3d. Stainless steels


Recall Feynman: 12-saal ke bachche ko samjhao

Socho school trip ke liye chaar backpacks hain. Ek normal dinon ke liye super light hai (aluminium). Ek lambi hike ke liye light aur tough hai (titanium). Ek campfire ke paas baith sakta hai bina pighle (nickel superalloy). Ek sasta hai aur baarish mein rust nahi karega (stainless steel). Tum ek backpack nahi laate — tum din ke hisaab se sahi wala uthate ho. Metals tab tough hote hain jab unke andar tiny lumps aur walls hote hain, kyunki "cracks" (dislocations) unpe trip karte hain jaise obstacle course mein. Lekin campfire ke paas (turbine heat), walls khud soft ho jaate hain aur slide karte hain — isliye best hot parts ek giant smooth crystal hote hain jisme koi walls nahi hoti.


Flashcards

Aerospace metal selection mein kaun si ek quantity govern karti hai?
Mass-specific strength, σ/ρ (strength per unit mass); weight-specific σ/(ρg) hoti hai lekin comparisons mein g cancel ho jaata hai.
2xxx Al alloys (jaise 2024) mein main alloying element kya hai?
Copper (Cu).
7xxx Al alloys (jaise 7075) mein main alloying element kya hai?
Zinc (Zn), Mg ke saath.
Fatigue-critical fuselage mein 7075 ki jagah 2024 kyun use karte hain?
2024 ki fracture toughness aur stress-corrosion resistance better hai.
Ti-6Al-4V ki composition ka matlab kya hai?
~6 wt% Al + 4 wt% V; Al, α (HCP) ko stabilize karta hai, V, β (BCC) ko stabilize karta hai.
Al alloys vs Ti vs stainless vs Ni superalloys ki approximate max service temperature kya hai?
~150 °C, ~400 °C, ~600 °C, ~1000 °C+.
Ni superalloys mein strengthening precipitate ka naam batao.
γ′ = Ni₃(Al,Ti), ordered, FCC γ matrix ke saath coherent.
Hall–Petch relation state karo.
σ_y = σ₀ + k·d^(−1/2); chhota grain → zyada yield.
Top turbine blades single crystals kyun hote hain?
High T par grain boundaries creep/sliding cause karti hain; unhe hatane se creep suppress hota hai.
Steel ko "stainless" kya banata hai?
≥10.5% Cr ek self-healing passive Cr₂O₃ film banata hai.
Inconel aur Hastelloy mein kya difference hai?
Inconel (Ni-Cr-Fe) high T par oxidation/creep ke liye; Hastelloy (Ni-Mo-Cr) extreme corrosion ke liye.
Precipitates ke past bowing ke liye Orowan stress kya hai?
τ = Gb/L; chhoti spacing L → zyada strong.
T6 temper kya hai?
Solution-treated + maximum strength ke liye peak-aged.
Peak-aged strength maximum kyun hoti hai, monotonic kyun nahi?
Cutting (∝r) aur bowing (∝1/L) ke beech crossover; over-aging particles ko coarsen karta hai, L badhata hai.

Connections

  • Dislocations and Slip
  • Precipitation Hardening
  • Hall–Petch Strengthening
  • Creep and High-Temperature Deformation
  • Phase Diagrams (α–β Titanium)
  • Corrosion and Passivation
  • Fatigue and Fracture Toughness
  • Single-Crystal Turbine Blades

Concept Map

answered by

selects

selects

selects

selects

cold and light

light and hot

very hot turbine

cheap corrosion-proof

via

grain boundaries

age hardening

solid solution

Temp Stress Weight need

Specific strength sigma/rho

Al alloys 7075 2024

Ti-6Al-4V

Ni superalloys Inconel

Stainless steel

Airframe skin

Structure engine parts

Turbine blades

Structural parts

Strength = block dislocations

Four mechanisms

Hall-Petch sigma d^-1/2